%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% \sect{State equations derived from $Z(T)$} Make sure you'r well aware of the basic equations of the canonical ensemble, and knows how to prove those equations for the state functions. % % \[\left(*\right) Z\left(\beta,X\right)\equiv \sum_{r}e^{-\beta E_{r}}\] % % % % \[E=-\frac{\partial \ln Z}{\partial \beta}\] % % % % \[y=\frac{1}{\beta}\,\frac{\partial \ln Z}{\partial X}\] % % % % \[F\left(T,X\right)\equiv -\frac{1}{\beta}\ln Z\left(\beta,X\right)\] % % % % \[S=-\frac{\partial F}{\partial T}\] % % More definitions (Heat capacity) ${C_{x}\equiv \frac{\partial E}{\partial T}|_{X}}$ (Generalized susceptibility) ${\chi\equiv \frac{\partial y}{\partial X}}$ (*) for a classical particle % % \[\sum_{r}\mapsto \int \frac{dxdp}{2\pi}\,\,E_{r}\mapsto H\left(X P\right)\] % %